Overview:
Standard NI serial hardware modules are limited to a maximum of 8 data bits per serial frame. This is a fixed hardware constraint and cannot be changed through software configuration.
If your application requires transmitting or receiving more than 8 bits per frame, you can implement a custom serial protocol on an FPGA target using digital I/O lines. CompactRIO controllers and PXIe FPGA modules both support this approach. Because the FPGA provides direct, cycle by cycle control over the state of each digital output, you can define frames of any bit width (10, 12, 16, 32, or more) and clock each bit out at a precise, configurable rate.
This technique can also serve as the foundation for building a full UART style communication scheme if your application requires start/stop bit framing, parity, and standard baud rates, however this article does not expand on this approach.