Solution
The pulsing capability of an SMU is hardware-dependent, not all SMUs support this mode. The SMU should have an appropriate circuitry to be able to pulse voltage or current. It is well described in the following article:
High-Power IV Characterization Using Pulsed SMU Output
The PXIe-4163 doesn't support any kind of pulsing. If it does then the appropriate information should be presented in the SMU's documentation.
For example, the PXIe-4139 does support pulsing, and if we compare the PXIe-4163 and PXIe-4139 documentation (both Specification and User Manual) we will see the difference:
PXIe-4163 Specifications
PXIe-4139 Specifications
PXIe-4163 Overview
PXIe-4139 Overview
You can see another confirmation at the end of this page too (see under the Support for Pulsing topic):
Support for Pulsing