You should be able to change the baud rate during runtime by filling in the BaudRate numeric control and click the change baudrate boolean button.
Please note that this is only possible in LabVIEW with previous versions of XNET which are older than the 2024 Q4 release, and not using the XNET C API. In this case, to change the Baud Rate, the session must be stopped completely and started again.
It is possible to change the baud rate with the XNET C API with the XNET 2024 Q4 release.