Solution
If you do not see any change in the LabVIEW project, this means that your new XML file is not taken into account by your device. Actually, the device in the LabVIEW project is indexing a special directory that is supposed to host the XML file. After importing the new XML file, it is possible that the your device keeps indexing the old XML in the Directory.
Please go to the following directory C:\Program Files (x86)\National Instruments\Shared\IndComECAT\DD and delete the old XML file and try to import your new XML file again. After that, you should be able to see the update made in your file.