Solution
The theoretical device limit for an EtherCAT network is 65,535 slaves, and Fast Ethernet (100 Mbit/s) limits are similarly high. The real limiting factor in the maximum number of devices in this system is the number of I/O channels you are deploying, the speed of the controller, and the application you are running.
Refer to the document Expansion I/O for LabVIEW RIO Systems: An In-Depth Comparison for more information.